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Lightning Experience Override on Opportunity not working on iPhone
I have setup a lightning detail page in the lightning app builder and made it my org wide default page. On the opportunity object setup page for button and links, there is a Visualforce page on the View that is set as the override page. In the screenshot bvelow you can see my setup. When i go to my iPhone app and navigate to an opportunity it still shows the visualforce page? I thought the Lightning Experience Override would allow me to see the Lightning page on my mobile device? I
Is there anyway to remove the visualforce page from the View override and give certain users access to that visualforce page via apex, etc?

Is there anyway to remove the visualforce page from the View override and give certain users access to that visualforce page via apex, etc?
Check Lightning component and choose the page for Mobile Override then refresh the page to see the changes.
https://help.salesforce.com/articleView?id=links_customize_override.htm&type=0
Please mark it as solved if my reply was helpful. It will make it available for other as the proper solution.
Best Regards
Sandhya