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Force.com Migration Guide now available!
The salesforce.com Development as a Service team has just released the
Force.com Migration Guide, an instruction manual for using the
Force.com Migration Tool to move metadata between your Salesforce
organizations.
View the Force.com Migration Guide online or download the PDF, or visit the Force.com Documentation Library for a complete list of online product documentation.
Perhaps posts like these could be made stickies so they don't get lost in the noise of these forums.