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As you have stated that visualforce tab is not listed, make sure you have added the tab from mobile navigation to appear in Salesforce1 app.
Setup Menu>Mobile Administration>Mobile Navigation .Select the tab from the Available ones and move it to the Selected Tabs.
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https://help.salesforce.com/apex/HTViewHelpDoc?id=customize_sf1_visualforce.htm&language=en_US
As you have stated that visualforce tab is not listed, make sure you have added the tab from mobile navigation to appear in Salesforce1 app.
Setup Menu>Mobile Administration>Mobile Navigation .Select the tab from the Available ones and move it to the Selected Tabs.